Calubian has 53 barangays 30 of which are scattered along its coastal side while the rest are being distributed on its very rugged terrain. The following are the different barangays which are listed alphabetically;
Abanilla, Anislagan, Bunacan, Cabalquinto, Cabradilla, Caneja , Cantonghao, Caruyucan, Casiongan , Cristina, Dalumpines, Don Luis Dulao , Enage , Espinosa, F. E. Marcos, Garganera, Garrido ,Guadalupe, Gutosan, Herrera, Igang, Inalad , Jubay, Juson, Kawayan Bugtong, Kawayanan, Labtic, Laray, Limite, Mahait, Malobago, Matagok, Nierras, Nipa, Obispo, Padoga, Pagatpat , Pal-og , Pangpang, Patag, Pates , Petrolio , Railes , Tabla, Tagharigue, Tuburan, T. Poblacion, Ul-og, Veloso, Villahermosa Villalon, Villanueva
